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Material Safety Datasheet

Envirogel (Indicating Silica Gel)

MCS/101/01/MSDS  Issue 2

1.

Product Identification

Name Envirogel
Company Brownell Ltd
Address

Unit 2, Abbey Road Industrial Park

Commercial Way

Park Royal, London NW10 7XF

Telephone number

Fax number

Emergency phone

+44 (0)20 8965 9281

+44 (0)20 8965 3239

+44 (0)20 8838 8408


2.

Composition/Information on the components

Chemical Description

Orange to Green Indicating Silica Gel

Formula

SiO2

CAS (R Phrase Classification)

112926-00-8 amorphous silica 98.2%, activated colouring agent 0.2% max.


3.

      

Health Hazard Identification

Do not breathe dust or exceed the exposure limits


4.

      

First Aid Measures

Inhalation

Remove from source of exposure.

Skin Contact

Wash spillage from skin with soap and water

Eyes Contact Wash immediately with copious amounts of water and obtain medical attention.
Ingestion Wash out mouth with water. If large amount swallowed or symptoms develop

5.

Fire Fighting Measures

 

        

Extinguishing Media

Not applicable. Inorganic compound. Not combustible.


6.

Accidental Release Measures

Personnel Precautions

Do not inhale. Wear appropriate protective clothing. Dust mask essential if conditions are dusty. See section 8 for exposure limits.

Spillages

Contain spillage. Collect in suitable containers for recovery or disposal.

During collection avoid creating dust.


7.

Handling and Storage

Handling

Avoid creating any dust. Do not smoke. During handling electrostatic charges can accumulate (see BS 5958 for advice on the control of static.)

Storage All containers must be closed air tight and kept in a dry place

8.

Exposure Control / Personal Protection

Occupational Exposure Standards:
Synthetic amorphous silica

Silica amorphous, total inhalable dust: UK EH40: OES 6mg/m3 8h TWA.

Silica amorphous, respirable dust: UK EH40: OES 2.4mg/m3 8h TWA.

Silica Gel: ACGIH: TLV 10mg/m3 8h TWA.

Activation agent: ACGIH: 0.5mg/m3 8h TWA.

Engineering Control Measures Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (dilution and ocal exhaust), and control of process conditions.
Respiratory Protection Avoid inhalation of dust. Wear suitable respiratory protective equipment if working in confined spaces with inadequate ventilation or whenever there is any risk of the exposure limits being exceeded.

Hand Protection

Eyes Protection

Protection During Application

Wear protective gloves.

Wear suitable eye protection.

Handle in well ventilated conditions in accordance with good industrial hygiene and safety practices.


9.

Physical and Chemical Properties

Aspect

Colour

Odour

pH

Melting Point (oC)

Boiling Point

Flash Point

Explosion Limits

Bulk Density

Solubility in Water

Thermal Decomposition

Beads

Dry: yellow/orange Saturated: Green

Odourless

2-10 at 5% w/w in water

>1000

Not Applicable

Not Applicable

Not Applicable

720kg per cu meter (typical)

less 1.0% in weight

Stable except when saturated water released during regeneration


10.

Stability and Reactivity

        

Stability

Conditions to Avoid

Materials to Avoid

Hazardous Decomposition 

Hygroscopic

High temperatures in excess of 155oC

None known

Hygroscopic material


11.

Toxicological Information

Toxicity The lethal dose for humans for synthetic amorphous silica is estimated at over 15,000mg/kg.
Health Effects Inhalation Synthetic amorphous silica gel has little adverse effect on lungs and does not produce significant disease or toxic effect when exposure is kept below the permitted limits. However existing medical conditions (eg asthma, bronchitis) may be aggravated by exposure to dust. Effects of dust may be greater, and occur at lower levels of exposure in smokers compared to non-smokers.
Eye Contact Dust may cause discomfort and mild irritation.
Skin Contact Dust may have a drying effect on the skin.
Carcinogenicity Amorphous silica is not classifiable as to its carcinogenicity to humans (Group 3).

12.

Ecological Information

        

Ecotoxicity

Synthetic amorphous silica is virtually inert and has no known adverse effect on the environment.


13.

Disposal

Product Disposal        

Product can be reactivated in an oven for re-use.

This material is not classified as hazardous waste under EEC Directive 91/689/EEC.

Dispose of in accordance with all applicable local and national regulations.

This material is not classified as special waste under UK Special Waste Regulations 1996 and can be disposed of by landfill at an approved site.


14.

Transport Information

        

UN Class

Not classified as dangerous goods under the United Nations Transport Recommendations.


15.

Information on Regulation

EC Classification

S phrases

This product is not classified as dangerous.

Handle in accordance with good industrial hygiene and safety practices.

Avoid inhalation of dust.

EINECS Listing

TSCA Listing

AICS Listing

DSL/NDSL (Canadian) Listing

Preparation – all components listed

Mixture – all components listed

Mixture – all components listed

Mixture – all components listed


16.

Other Information

         

         

MSDS first issued

18th April 2000

MSDS first revision 20th November 2002

The information provided in the Material Safety Data Sheet is correct to the best of our knowledge at the date of publication. This document is intended as a guide for safe handling, storage and use in known industrial applications.
 

Specification No. MCS/101/01/MSDS

MSDS According to EEC 91/155

 

 

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